Electric Literature of 15746-57-3, An article , which mentions 15746-57-3, molecular formula is C20H16Cl2N4Ru. The compound – Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II) played an important role in people’s production and life.
Thiolato-bridged RuIIAgRuII trinuclear complex composed of bis(bipyridine)ruthenium(II) units with chelating 2-aminoethanethiolate: Conversion to a disulfide-bridged RuIIRu II dinuclear complex
The reaction of [Ru(solvent)2(bpy)2]2+ (bpy = 2,2?-bipyridine) with Haet (2-aminoethanethiol) in ethanol/water in the presence of Ag+ gave a thiolato-bridged RuIIAgRu II trinuclear complex, [Ag{Ru-(aet)(bpy)2} 2]3+, in which two [RuII(aet)(bpy) 2]+ units are linked by an AgI atom. When this complex was treated with HCl in acetonitrile/water, a disulfide-bridged Ru IIRuII dinuclear complex, [Ru2(cysta)(bpy) 4]4+ (cysta = cystamine), was produced as a result of the removal of an AgI atom and the autoxidation of thiolato groups. It was found that the dinuclear structure in [Ru2(cysta)-(bpy) 4]4+ is reverted back to [Ag{Ru(aet)(bpy) 2}2]3+ by treatment with Ag+ assisted by Zn reduction.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 15746-57-3, help many people in the next few years., Electric Literature of 15746-57-3
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI