A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Article£¬once mentioned of 10049-08-8, Application In Synthesis of Ruthenium(III) chloride
Mechanism of Ru(III) catalysis in N-bromoacetamide oxidation of some glycols in perchloric acid media
The kinetics of ruthenium(III) chloride catalysis in the oxidation of diethylene glycol (DG) and methyl diethylene glycol (MDG) by N-bromoacetamide (NBA) in perchloric acid media are reported. The reactions follow identical kinetics, showing zero-order dependence on NBA, but first-order on each of H+, Ru(III) and Cl- ions. The first-order kinetics with respect to glycol at low concentrations shifts to zero-order at higher concentrations. A negative effect of ionic strength is observed, while successive addition of acetamide, D2O and mercuric acetate shows zero effect on the reaction rate.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Application In Synthesis of Ruthenium(III) chloride. In my other articles, you can also check out more blogs about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI