In an article, published in an article, once mentioned the application of 20759-14-2, Name is Ruthenium(III) chloride hydrate,molecular formula is Cl3H2ORu, is a conventional compound. this article was the specific content is as follows.Formula: Cl3H2ORu
Trivalent iron and ruthenium complexes with a redox noninnocent (2-Mercaptophenylimino)-methyl-4,6-di-tert-butylphenolate(2-) Ligand
The 3,5-di-tert-butyl substituted N-(salicylidene)-o-mercaptoaniline (H2L) ligand reacted with equimolar amounts of FeBr2 and 2 equiv of triethylamine in air affords [FeIII(L-L)Br]0 (1), where (L-L)2- is a pentacoordinate ligand formed from the oxidative dimerization of L2- via disulfide bridge formation. Reaction of H2L with RuCl3 ¡¤ H2O and NEt3 gives a dark green-brown dinuclear complex, [Ru III2(L)2Cl2(NCCH3) 2]0 (2). Both complexes have been characterized by X-ray crystallography. A Ru-Ru single bond is evident in 2. Complex 1 has also been characterized by electron paramagnetic resonance and Moessbauer spectroscopies and magnetic susceptibility measurements that identify a high-spin Fe(III) (S = 5/2) center. Diamagnetic 2 is successively twice reversibly one-electron oxidized to produce [Ru III2(L¡¤)(L)Cl2(NCCH 3)2]+, [2]+ (S = 1/ 2), and [RuIII2(L¡¤) 2Cl2(NCCH3)2]2+, [2] 2+ (S = 0). Spectroelec-trochemical and electron paramagnetic resonance measurements identify these as ligand-based oxidations affording o-coordinated phenoxyl radicals. DFT calculations on the electron transfer series corroborate this result and that the Ru-Ru single bond is retained throughout this series.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI