The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, Recommanded Product: 37366-09-9
Reactions of the Lithiated Diphosphine tBu2P?P(SiMe3)Li with [(eta6-C6H6)RuCl2]2in the Presence of Tertiary Phosphines
tBu2P?P(SiMe3)Li reacted with [(eta6-C6H6)RuCl2]2at ?40 C in the presence of PR3(PR3= PEt3, PEt2Ph, PEtPh2) by the nucleophilic addition of the tBu2P?P(SiMe3) moiety to the benzene ring to yield solely the complexes [(R3P)2Ru(Cl){eta5-C6H6(Me3SiP?PtBu2)}] (1). These products decomposed slowly at ambient temperature to yield benzene, Ru clusters, and small amounts of the dinuclear ruthenium complexes [{(R3P)2Ru}2(mu,eta2:2-P2)2Ru(PR3)2] (Ru?Ru) (6). Single-crystal X-ray diffraction studies of [(PhEt2P)2Ru(Cl){eta5-C6H6(Me3SiP?PtBu2)}] (1b) and [(Ph2EtP)2Ru(Cl){eta5-C6H6(Me3SiP?PtBu2)}] (1c) revealed that the addition of the tBu2P?P(SiMe3) group occurred through an exo pathway. Complex 6a (R = Et) displays a planar rectangular P4system consisting of two P2units and a Ru?Ru distance that lies in the range of a single bond.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.Recommanded Product: 37366-09-9, you can also check out more blogs about37366-09-9
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI