Reference of 10049-08-8, An article , which mentions 10049-08-8, molecular formula is Cl3Ru. The compound – Ruthenium(III) chloride played an important role in people’s production and life.
Nitrosyl ruthenium complexes with general formula [RuCl3(NO)(P-P)] (P-P = {PPh2(CH2)nPPh2}, n = 1-3 and {PPh2-CH = CH-PPh2}). X-ray structure of [RuCl3(NO){PPh2(CH2)3PPh 2}]
Ruthenium(II) complexes with general formula [RuCl3(NO)(P-P)] were obtained in the solid state, where P-P = PPh2(CH2)nPPh2 (n = 1-3) and PPh2-CH = CH-PPh2. The 31P NMR spectra of these compounds measured in CH2Cl2 showed only singlets, consistent with a fac configuration containing two equivalent phosphorus atoms. However the X-ray diffraction data show that the [RuCl3(NO){PPh2(CH2)3PPh 2}] complex crystallizes in a mer configuration, where one of the phosphorus atoms is trans to the NO group, in a slightly distorted octahedral geometry. Copyright
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI