Related Products of 114615-82-6, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 114615-82-6, C12H28NO4Ru. A document type is Article, introducing its new discovery.
Oxidation of primary alcohols to aldehydes with oxygen catalysed by tetra-n-propylammonium perruthenate
The liquid-phase oxidation of a series of saturated and unsaturated non-allylic alcohols to aldehydes with oxygen or air catalysed by tetra-n-propylammonium perruthenate (TPAP, represented as [(n-Pr)4N]RuO4) at 80-110 C is shown to proceed with selectivities of 72-91% at 55-80% alcohol conversion. The unsaturated alcohols, such as 9-decenol, 9-octadecenol and beta-citronellol, give the corresponding unsaturated aldehydes without competing double bond attack. The time course of oxidation indicates a complex reaction mechanism. The results on oxidation of a test alcohol, t-Bu(Ph)CHOH, suggest that one-electron processes do not play an important role in the TPAP-catalysed aerobic oxidation of alcohols.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI