Discovery of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 32993-05-8, help many people in the next few years., 32993-05-8

32993-05-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.

Electrochemical studies on (eta5-C5H5)Ru(PPh3)(L)X (L = PPh3, pyridine; X = H, Cl) and (eta5-C5H5)Ru2Cl in non-aqueous solvents

The redox properties of a series of cyclopentadienylruthenium compounds, (eta5-C5H5)Ru(PPh3)(L)X (L = PPh3, pyridine; X = H, Cl) and (eta5-C5H5)Ru2Cl,have been studied in different nonaqueous solvents (MeCN, THF, CH2Cl2).The ruthenium(II)/ruthenium(III) couple is observed in the potential range of +0.05 V to +0.70 V (vs SCE) depending upon the type of ligands and the solvent medium.The E0298 values vary in the order THF > CH2Cl2 > MeCN.While the couple is nearly reversible in MeCN, the electron transfer is sluggish (i.e., quasireversible) in other solvents.The E0298 values follow the order: (eta-Cp)Ru-2Cl > (eta-Cp)Ru(PPh3)(py)Cl <* >(eta-Cp)Ru(PPh3)2Cl > (eta-Cp)Ru(PPh3)2H(eta-Cp = eta5-C5H5).

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 32993-05-8, help many people in the next few years., 32993-05-8

Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI