Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), 32993-05-8.
Ruthenium(II), rhodium(III) and iridium(III) based effective catalysts for hydrogenation under aerobic conditions
The new cationic mononuclear complexes [(eta6-arene)Ru(Ph-BIAN)Cl]BF4 [eta6-arene = benzene (1), p-cymene (2)], [(eta5-C5H5)Ru(Ph-BIAN)PPh3]BF4 (3) and [(eta5-C5Me5)M(Ph-BIAN)Cl]BF4 [M = Rh (4), Ir (5)] incorporating 1,2-bis(phenylimino)acenaphthene (Ph-BIAN) are reported. The complexes have been fully characterized by analytical and spectral (IR, NMR, FAB-MS, electronic and emission) studies. The molecular structure of the representative iridium complex [(eta5-C5Me5)Ir(Ph-BIAN)Cl]BF4 has been determined crystallographically. Complexes 1-5 effectively catalyze the reduction of terephthaldehyde in the presence of HCOOH/CH3COONa in water under aerobic conditions and, among these complexes the rhodium complex [(eta5-C5Me5)Rh(Ph-BIAN)Cl]BF4 (4) displays the most effective catalytic activity.
32993-05-8, A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI