15746-57-3. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru.
Unexpected High Second-Order Nonlinear Optical Activity of Metal Complexes with Three-Branched Hexadentate 2,2?-Bipyridine Ligands
Two hexadentate bipyridine ligands and their RuII and NiII complexes were prepared. The helical alignment of the three electron-donor?pi-bridge?electron-acceptor (d-pi-A) single-strands with bundle architecture in cooperation with the metal center can strongly enhance the nonlinear optical (NLO) properties. The complexation of the novel cage-type hexadentate ligands with a paramagnetic NiII-core almost doubles the betaHRS values compared with the corresponding diamagnetic RuII complexes. The hyper-Rayleigh scattering (HRS) was performed with a highly sensitive setup for simultaneous discrimination between multi-photon fluorescence and the molecular first hyperpolarizability.
15746-57-3, The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 15746-57-3 is helpful to your research.
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI