10049-08-8. Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 10049-08-8, Name is Ruthenium(III) chloride,introducing its new discovery.
Ruthenium(III) catalyzed oxidation of sulfanilic acid by diperiodatocuprate(III) in aqueous alkaline medium. A kinetic and mechanistic approach
The kinetics of ruthenium(III) catalyzed oxidation of sulfanilic acid by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of (0.50 mol dm-3) has been studied spectrophoto-metrically. The reaction between sulfanilic acid and DPC in alkaline medium exhibits 1: 4 stoichiometry (sulfanilic acid: DPC). The reaction is first order with respect to [DPC] and [RuIII] and has less than unit order both in [sulfanilic acid] and [alkali]. The active species of catalyst and oxidant have been identified. Intervention of free radicals was observed in the reaction. The main products were identified by spot test and IR. Probable mechanism is proposed and discussed. The reaction constants involved in the different steps of the mechanism are calculated. The activation parameters with respect to the slow step of the mechanism are computed and discussed. Thermodynamic quantities are also determined.
10049-08-8, If you are hungry for even more, make sure to check my other article about 10049-08-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI