15529-49-4, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Dichlorotris(triphenylphosphino)ruthenium (II), cas is 15529-49-4,the ruthenium-catalysts compound, it is a common compound, a new synthetic route is introduced below.
A 50 ml three-necked flask equipped with a stirring reflux device was charged with 1 mmol of 2-diphenylphosphineaniline,1.1 mmol of p-methylbenzyl alcohol, 1 mmol of 2-diphenylphosphinophenyl ether, 1 mmol of RuCl2 (PPh3) 3, 1.4 mmol of triethylamine and 20 ml of dioxane were added and the mixture was heated at 110 C for 12 h under a nitrogen atmosphere.After cooling and filtering, the resulting solid was recrystallized from a mixed solvent of CH 2 Cl 2 and petroleum ether to give product 14 in a yield of 86%.
Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Dichlorotris(triphenylphosphino)ruthenium (II), 15529-49-4
Reference£º
Patent; Luoyang Normal College; Li Hongmei; Xu Chen; Zu Enpu; Xiao Zhiqiang; Han Xin; (12 pag.)CN104804048; (2017); B;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI