301224-40-8, Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 301224-40-8, name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride This compound has unique chemical properties. The synthetic route is as follows.
HII 65 HII (200mg) and P(0’Pr)3 (5eq) were stirred in for 72h. The crude 65 was recrystallised from DCM/pentane. (400MHz, 298K): 16.05 (d, 1 H, J = 35.3 Hz, C=CH), 10.24 (d, 1 H, J = 9.7 Hz, Ph-H), 6.87-6.83 (m, 2H, Ph-H), 6.78 (s, 1 H, Ph-H), 6.61 (s, 1 H, Ph-H), 6.19-6.16 (m, 2H, Ph- H), 4.67 (brs, 2H, PO-CH-CH3), 4.09-4.06 (m, 1 H, Ph-0-CH-CH3), 4.04 (brs, 1 H, PO- CH-CH3), 3.43-3.40 (m, 1 H), 3.16-3.02 (m, 3H), 2.89 (s, 3H, Mes-CH3), 2.58 (s, 3H, CH3), 2.46 (s, 3H, CH3), 2.42 (s, 3H, CH3), 2.18 (s, 3H, CH3), 1.92 (s, 3H, CH3), 1.48- 0.80 (m, 24H, PO-CH-CH3).31P{1H} (121.49MHz, 298K): 128.7 (s)
With the complex challenges of chemical substances, we look forward to future research findings about 301224-40-8,belong ruthenium-catalysts compound
Reference£º
Patent; UNIVERSITY COURT OF THE UNIVERSITY OF ST ANDREWS; CAZIN, Catherine; WO2011/117571; (2011); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI