203714-71-0, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 203714-71-0, name is Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II) This compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.
NHC ligand precursor 21 (9 mg, .03 mmol), KOz-Bu(F6) (6 mg, .03 mmol), and ruthenium complex 911 (13 mg, .02 mmol) were all combined in CgDbeta in a screw cap NMR tube in a glove box. The NMR tube was removed and heated at 600C for 2.5 hour in a fume hood. Conversion to catalyst 22 was determined to be 14% by proton NMR. 1H NMR (300 MHz, CDCl3) delta 17.19 (IH, s).
203714-71-0, 203714-71-0 Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II) 10941020, aruthenium-catalysts compound, is more and more widely used in various fields.
Reference£º
Patent; MATERIA, INC.; CALIFORNIA INSTITUTE OF TECHNOLOGY; WO2007/75427; (2007); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI