301224-40-8, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 301224-40-8, name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride This compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.
Take Grubbs-HoveydaII catalyst (464.0mg, 0.74mmol),Compound II (201.0 mg, 0.9 mmol,) prepared in Example 1 was placed in a 25 mL round bottom flask.Add 15 mL of dry THF and stir at 800 r / min at room temperature for 30 min.After the reaction was completed, the solvent was dried with a vacuum pump to obtain a brown-red solid.Add n-hexane to the solid and stir thoroughly. At this time, the color of n-hexane will turn red. Centrifuge the mixture, discard the liquid, and dry the solid.Compound III (385 mg, yield: 70.6%) was obtained as a brown solid powder.
301224-40-8, As the paragraph descriping shows that 301224-40-8 is playing an increasingly important role.
Reference£º
Patent; Jilin Chemical College; Yu Xiaobo; Geng Shudong; Liu Guanchen; (14 pag.)CN110563769; (2019); A;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI