As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is Dichlorotris(triphenylphosphino)ruthenium (II), and cas is 15529-49-4, its synthesis route is as follows.
To [RuCl2(PPh3)3] (360 mg, 0.375 mmol) was added a solution of la (100 mg, 0.375 mmol) in 5 ml of CH2C12 with stirring. The resulting burgundy solution was stirred at room temperature. An analysis of the reaction mixture by 31 P NMR spectroscopy after 1 hour revealed complete conversion of the starting material into the product, indicated by a resonance at delta 40.9 ppm, and the presence of free PPh3, delta -5.5 ppm). After reacting for a total of 2 hours, the burgundy solution was concentrated to approximately 40% of its original volume, followed by layering with diethyl ether (22 ml). After six days, the mother liquor was decanted, leaving a light pink powder. This powder was transferred to a filter frit, washed with diethyl ether (3 x 10 ml) and vacuum dried overnight. Isolated yield of complex A-l : 236 mg (90%). Elem. Anal: Calc’d for (0418) C32H37Ci2N2OPRuS (700.66): C, 54.86; H, 5.32; N, 4.00%. Found: C, 54.96; H, 5.19; N, 4.03%. 31P{1H} (162 MHz, CD2C12, r.t.): delta 41.0 (s). 1H NMR (400 MHz, CD2C12, r.t.): delta 2.81 (vt, J~ 14 Hz, 1H), 2.93-3.07 (m, 2H), 3.16-3.39 (m, 7H), 3.46-3.58 (m, 2H), 3.62-3.68 (m, 3H), 3.81 (vt, J~ 13 Hz, 1H), 5.88 (brs, NH, 1Eta), 6.98 (t, J~ 8 Hz, 2H), 7.20-7.33 (m, 12H), 7.72 (vt, J~ 9 Hz, 6H). 13C{1H} (100.5 MHz, CD2C12, r.t.): delta 44.9 (s, 1C), 47.0 (s, 1C), 48.4 (s, 1C), 52.9 (s, 1C), 54.7 (s, 1C), 59.3 (s, 1C), 60.2 (s, 1C), 61.6 (s, 1C), 127.1 (d, JC-P = 8.7 Hz, 6Cmeta, Pi), 127.9 (s, 2Cmeta, Ph), 128.5 (d, JC-P = 1.5 Hz, 3Cpara, PPh3), 128.6 (s, Cpam, Ph), 133.1 (s, (0419) 2Cortho, Ph), 134.5 (d, Jc-P = 9.5 Hz, 6Cortho, Pi), 134.8 (s, 1C^0, Ph), 137.7 (d, J= 36 Hz, ICipso); 31P{1H} (162 MHz, CDC13, r.t.): delta 40.3 (s). 1H NMR (400 MHz, CDC13, r.t.): delta 2.74 (vt, J~ 14 Hz, 1H), 2.94-3.02 (m, 2H), 3.11-3.45 (m, 9H), 3.51-3.70 (m, 5H), 3.78 (vt, J~ 13 Hz, 1H), 5.87 (brs, NH, 1Eta), 6.95 (t, J~ 8 Hz, 2H), 7.15-7.32 (m, 12H), 7.72 (t, J~ 9 Hz, 6H). 13C{1H} (100.5 MHz, CDC13, r.t.): delta 45.2 (s, 1C), 47.2 (s, 1C), 48.5 (s, 1C), 52.8 (s, 1C), 54.8 (s, 1C), 58.9 (s, 1C), 60.2 (s, 1C), 61.6 (s, 1C), 127.3 (d, Jc_P = 8.7 Hz, 6Cmeta, Pi), 128.1 (s, 2Cmeta, Ph), 128.7 (d, Jc-P = 1.5 Hz, 3Cpara, Pi), 128.8 (s, Cpara, Ph), 133.2 (s, 2Cortho, Ph), 134.6 (d, Jc-P = 9.5 Hz, 6Cortho, Pi), 134.5 (s, lCipso, Ph), 137.1 (d, J= 36 Hz, 3Cipso).
15529-49-4, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,15529-49-4 ,Dichlorotris(triphenylphosphino)ruthenium (II), other downstream synthetic routes, hurry up and to see
Reference£º
Patent; LOS ALAMOS NATIONAL SECURITY, LLC; DUB, Pavel, A.; GORDON, John, Cameron; WO2015/191505; (2015); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI