50982-12-2, In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. Dichloro(cycloocta-1,5-diene)ruthenium(II), cas is 50982-12-2,the ruthenium-catalysts compound, it is a common compound, a new synthetic route is introduced below.
Na2[7,10-nido-C2B10H12] was dissolved in degassed THF (45 mL) giving a purple solution. Excess Na was removed from the reduced carborane solution to give a colourless solution which was then transferred into a Schlenk tube containing [RuCl2(COD)]x (0.780 g, 2.78 mmol) and a large excess of naphthalene. The resulting brown mixture was heated at reflux for 90 min then allowed to cool to room temperature. The brown mixture was filtered through a short silica column eluting with DCM to afford a brown solution, removal of solvent from which yielded a brown solid. This was further purified by column chromatography (1:2 DCM:40-60 petroleum ether), giving a yellow band, followed by preparative TLC (2:1 DCM:40-60 petroleum ether, Rf 0.38) yielding solid. C12H20B10Ru requires C 38.59, H 5.40. Found: C 39.48, H 4.87%.
Chemical properties determine the actual use. Each compound has specific chemical properties and uses. We look forward to more synthetic routes in the future to expand reaction routes of Dichloro(cycloocta-1,5-diene)ruthenium(II), 50982-12-2
Reference£º
Article; Scott, Greig; Ellis, David; Rosair, Georgina M.; Welch, Alan J.; Journal of Organometallic Chemistry; vol. 721-722; (2012); p. 78 – 84;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI