As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is Dichloro(cycloocta-1,5-diene)ruthenium(II), and cas is 50982-12-2, its synthesis route is as follows.
Separately, 200 ml of well dried tetrahydrofuran was fed to a 500 ml flask whose inside had been substituted by argon, and 5 g of dichloro(cyclooctadienyl)ruthenium was injected into the flask and well mixed with tetrahydrofuran to obtain a suspension. This suspension was cooled to -78 C. in a stream of argon, and 14 ml of a tetrahydrofuran solution of the above synthesized fluorocyclopentadienyl sodium was added dropwise to the above suspension over 1 hour. The obtained reaction mixture was further stirred at -78 C. for 3 hours and returned to room temperature under agitation over 12 hours. After the reaction mixture was let pass through a neutral alumina column in a stream of argon to be purified and concentrated, it was purified again by a neutral alumina column to obtain 0.4 g of bis(fluorocyclopentadienyl)ruthenium (yield rate of 8.4%).
50982-12-2, In the field of chemistry, the synthetic routes of compounds are constantly being developed and updated. I will also mention this compound in other articles.,50982-12-2 ,Dichloro(cycloocta-1,5-diene)ruthenium(II), other downstream synthetic routes, hurry up and to see
Reference£º
Patent; JSR Corporation; US2006/240190; (2006); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI