Name is Dichlorotris(triphenylphosphino)ruthenium (II), as a common heterocyclic compound, it belongs to ruthenium-catalysts compound, and cas is 15529-49-4, its synthesis route is as follows.,15529-49-4
Solid [Ru(PPh3)3Cl2] (200 mg, 0.21 mmol) was added to a methanol solution (30 ml) of H2L1 (153 mg, 0.42 mmol) and NaOAc(35 mg, 0.42 mmol). The mixture was boiled under reflux for 1 h and then cooled to room temperature. The red solid deposited was collected by filtration and dried in air. This material was dissolved in minimum amount of dichloromethane and transferred to a silica gel column packed with dichloromethane. The first yellow band moved with the eluent 1 : 4 mixture of dichloromethane/ n-hexane was discarded. The following red band containing the complex 1 was eluted with a 2 : 3 mixture of dichloromethane/ n-hexane. The red solution thus obtained was evaporated to dryness and the complex was collected as a dark red solid. The yield was 220 mg (78 %).
With the complex challenges of chemical substances, we look forward to future research findings about Dichlorotris(triphenylphosphino)ruthenium (II)
Reference£º
Article; Nagaraju, Koppanathi; Pal, Samudranil; Inorganica Chimica Acta; vol. 413; (2014); p. 102 – 108;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI