As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, and cas is 246047-72-3, its synthesis route is as follows.,246047-72-3
A suspension of 790 mg (0.93 mmol) of [RuCl2(PCy3) (ImH2Mes)(phenylmethy- lene)], 95 mg (0.96 mmol) copper chloride and 196 mg (1.03 mmol) 4-chloro-8-vinyl- quinoline in 70 ml methylene chloride was stirred at 300C for 90 min. The reaction mixture was evaporated to dryness and the isolated crude product purified by silica gel chromatography (hexane / ethyl acetat 5:2) and finally digested in 20 ml pentane at room temperature for 30 min to yield 311 mg (51%) of the title compound as green crystals. MS: 655.0 (M+). 1H-NMR (300 MHz, CD2Cl2): 2.35 (s, 6H); 2.39 (s, 12H); 4.04 (s, 4H); 7.00 (s, 4H); 7.25 (d, J=5.3Hz, IH); 7.43 (dd, J=8.2, 7.3Hz, IH); 7.56 (dd, J=7.1, 0.7Hz, IH); 8.13 (d, J=5.3Hz, IH); 8.41 (dd, J=8.2, 0.7Hz, IH); 16.95 (s, IH). Anal, calcd. for C31H32N3Cl3Ru: C, 56.93; H, 4.93; N, 6.42; Cl, 16.26. Found: C, 56.59; H, 5.04; N, 6.02; Cl, 15.49.
With the complex challenges of chemical substances, we look forward to future research findings about 246047-72-3,belong ruthenium-catalysts compound
Reference£º
Patent; F. HOFFMANN-LA ROCHE AG; WO2008/644; (2008); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI