As a common heterocyclic compound, it belongs to quinuclidine compound,Quinuclidine-4-carboxylic acid hydrochloride,40117-63-3,Molecular formula: C8H14ClNO295,mainly used in chemical industry, its synthesis route is as follows.,15529-49-4
A 50 ml three-necked flask equipped with a stirring reflux device was charged with 1 mmol of 2-diisopropylphosphineaniline,1.8 mmol of m-chlorobenzyl alcohol, 1 mmol of o-dicyclohexylphosphine benzene, 1 mmol of RuCl2 (PPh3) 3, 1.2 mmol of sodium hydroxide, 20 ml of dioxane and heating at 110 C. for 12 h under a nitrogen atmosphere, After filtration, the resulting solid was recrystallized from a mixed solvent of CH 2 Cl 2 and petroleum ether to give product 12 in a yield of 82%.
With the synthetic route has been constantly updated, we look forward to future research findings about Dichlorotris(triphenylphosphino)ruthenium (II),belong ruthenium-catalysts compound
Reference£º
Patent; Luoyang Normal College; Li Hongmei; Xu Chen; Zu Enpu; Xiao Zhiqiang; Han Xin; (12 pag.)CN104804048; (2017); B;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI