As a common heterocyclic compound, it belongs to quinuclidine compound,Quinuclidine-4-carboxylic acid hydrochloride,40117-63-3,Molecular formula: C8H14ClNO92,mainly used in chemical industry, its synthesis route is as follows.,15529-49-4
A 50 ml three-necked flask equipped with a stirring reflux device was charged with 1 mmol of 2-diphenylphosphineaniline,1.5 mmol of m-ethoxybenzyl alcohol, 1 mmol of bis (diphenylphosphinoethane), 1 mmol of RuCl2 (PPh3) 3, 1.5 mmol of sodium hydroxide and 20 ml of benzene at a temperature of 100 C for 24 h under a nitrogen atmosphere,After cooling and filtering, the obtained solid was recrystallized from a mixed solvent of CH 2 Cl 2 and petroleum ether to give product 4 in a yield of 86%.
With the complex challenges of chemical substances, we look forward to future research findings about Dichlorotris(triphenylphosphino)ruthenium (II),belong ruthenium-catalysts compound
Reference£º
Patent; Luoyang Normal College; Li Hongmei; Xu Chen; Zu Enpu; Xiao Zhiqiang; Han Xin; (12 pag.)CN104804048; (2017); B;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI