With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.
General procedure: The reaction of 2,6-diacetylpyridine mono(4-methoxyphenylthiosemicarbazone) ligand, HL1, prepared as described in reference 35, with RuCl2(PPh3)3 in 1:1M ratios was carried out, in presence of Et3N, in degassed toluene for 3hat room temperature under nitrogen atmosphere. The resulting brown solution was filtered and evaporated to dryness. The solid residue was washed with pentane and dried in vacuo. Further purification by recrystallization from DMSO led to single crystals which were studied by X-ray diffraction techniques.
15529-49-4, 15529-49-4 Dichlorotris(triphenylphosphino)ruthenium (II) 11007548, aruthenium-catalysts compound, is more and more widely used in various fields.
Reference£º
Article; Matesanz, Ana I.; Hernandez, Carolina; Perles, Josefina; Souza, Pilar; Journal of Organometallic Chemistry; vol. 804; (2016); p. 13 – 17;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI