246047-72-3, (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated
A suspension of 1.00 g (1.18 mmol) of [RuCl2(PCy3)(ImH2Mes)(phenylmethylene)] (commercially available from Sigma- Aldrich Inc., St. Louis, USA), 0.14 g (1.41 mmol) of copper chloride and 0.37 g (1.41 mmol) of 2-methyl-l-pyrrolidin-l-yl-2-(2-vinyl-phenoxy)- propan-1-one in 80 ml of dichloro methane was stirred for 90 min at 400C. The reaction mixture was evaporated to dryness at 40C/10 mbar. The residue was stirred in 25 ml of ethyl acetate for 15 min at room temperature. The dark green suspension was filtered and the filtrate concentrated to a total volume of 5 ml. To the green solution, 15 ml of pentane were added and the formed suspension was stirred for 30 min at room temperature and filtered. The filter cake was washed with 40 ml of pentane and dried at 25C/10 mbar over night to afford 0.68 g (80% yield) of the title compound as a green powder.MS: 723.2 (M+)., 246047-72-3
The synthetic route of 246047-72-3 has been constantly updated, and we look forward to future research findings.
Reference£º
Patent; F. HOFFMANN-LA ROCHE AG; WO2009/124853; (2009); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI