As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride, and cas is 301224-40-8, its synthesis route is as follows.,301224-40-8
General procedure: In a glove box, a flask was charged with Ru complex 4 or 5 and Ag salt 3. Anhydrous degassed CH2Cl2 was then added and the resulting mixture was stirred at room temperature for 3h in the dark. The solids were filtered off through a Celite layer and washed with anhydrous (2mL). The solution was diluted with anhydrous hexane (10mL) and remaining precipitated Ag salt was again filtered off. Evaporation of the solvents on a rotary vacuum evaporator (40C, 1h, 25kPa) and finally at oil pump vacuum (25C, 1h, 1kPa) gave the products 1 or 2.
With the complex challenges of chemical substances, we look forward to future research findings about 301224-40-8,belong ruthenium-catalysts compound
Reference£º
Article; Lipovska, Pavlina; Rathouska, Lucie; ?im?nek, Ond?ej; Ho?ek, Jan; Kola?ikova, Viola; Ryba?kova, Marketa; Cva?ka, Josef; Svoboda, Martin; Kvi?ala, Jaroslav; Journal of Fluorine Chemistry; vol. 191; (2016); p. 14 – 22;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI