With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.
General procedure: Synthesis of the ruthenium(II) Schiff base complexes (2a-d) was accomplished according to the following procedure: To a solution of Schiff base 1a-d in methanol was added dropwise a solution of NaOH in methanol and the reaction mixture was stirred for 2hat room temperature. The deprotonated ligand mixture was transferred by cannula to a 50-mL three-necked flask fitted with a reflux condenser containing the [RuCl2(PPh3)3] precursor, stirred mixture was refluxed for 4h. A yellow precipitate was then filtered and washed with methanol and ethyl ether and then dried in a vacuum.
15529-49-4, 15529-49-4 Dichlorotris(triphenylphosphino)ruthenium (II) 11007548, aruthenium-catalysts compound, is more and more widely used in various fields.
Reference£º
Article; Afonso, Maria Beatriz A.; Cruz, Thais R.; Silva, Yan F.; Pereira, Joao Clecio A.; Machado, Antonio E.H.; Goi, Beatriz E.; Lima-Neto, Benedito S.; Carvalho-Jr, Valdemiro P.; Journal of Organometallic Chemistry; vol. 851; (2017); p. 225 – 234;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI