Introduction of a new synthetic route about Dichlorotris(triphenylphosphino)ruthenium (II)

With the rapid development of chemical substances, we look forward to future research findings about 15529-49-4

Dichlorotris(triphenylphosphino)ruthenium (II), cas is 15529-49-4, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,15529-49-4

A mixture of [RuCl2(PPh3)3] (50 mg, 0.052 mmol) and bipy (10mg, 0.06 mmol) were charged in a two necked round bottomed flask and kept under vacuum for 15 min. 20 mL of dry acetone was then added and the brown mixture was stirred under argon atmosphere for approximately 30 min. A light yellowish-brown solid was precipitated that was filtered off, washed with diethylether (2 5 mL) and subsequently dried in vacuo. Yield: 90 %(40 mg). UV-Vis (e, Mu1 cm1): kmax (CH2Cl2) = 490 (5370), 350(9640).

With the rapid development of chemical substances, we look forward to future research findings about 15529-49-4

Reference£º
Article; Zacharopoulos, Nikolaos; Kolovou, Evgenia; Peppas, Anastasios; Koukoulakis, Konstantinos; Bakeas, Evangelos; Schnakenburg, Gregor; Philippopoulos, Athanassios I.; Polyhedron; vol. 154; (2018); p. 27 – 38;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI