(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, cas is 246047-72-3, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,246047-72-3
A suspension of 218 mg (0.26 mmol) of [RuCl2(PCy3) (ImH2Mes)(phenylmethy- lene)], 26 mg (0.26 mmol) copper chloride and 49 mg (0.29 mmol) 2-methyl-8-vinyl- quinoline in 17 ml methylene chloride was stirred at 300C for 90 min. The reaction mixture was evaporated to dryness and the isolated crude product purified by silica gel chromatography (hexane / ethyl acetat 7:3) and finally digested in 15 ml hexane at room temperature for 30 min to yield 157 mg (96%) of the title compound as green crystals. MS: 632.9 (M+). 1H-NMR (300 MHz, C6D6): 2.15 (s, 3H); 2.29 (s, 6H); 2.64 (s, 12H); 3.49 (s, 4H); 6.30 (d, J=8.4Hz, IH); 6.80 (t, J=7.3Hz, IH); 6.98 (s, 4H); 7.10 (d, J=8.4Hz, IH); 7.40 (d, J=8.1Hz, IH); 7.52 (d, J=7.0Hz, IH), 17.15-17.32 (br, IH). Anal, calcd. for C32H35N3Cl2Ru: C, 60.66; H, 5.57; N, 6.63; Cl, 11.19. Found: C, 60.33; H, 5.58; N, 6.27; Cl, 10.90.
With the rapid development of chemical substances, we look forward to future research findings about 246047-72-3
Reference£º
Patent; F. HOFFMANN-LA ROCHE AG; WO2008/644; (2008); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI