Day: September 8, 2020

15529-49-4, Dichlorotris(triphenylphosphino)ruthenium (II) is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

c) Preparation of the Complex Dichloro bis[3-(Diphenylphosphino)-1-propylamine]Ruthenium; ([RuCl2(L-2)2]). Under argon, a round-bottomed Schlenck flask, equipped with a magnetic stirring bar, was charged with RuCl2(PPh3)3 (1.028 g, 1.07 mmol) and with a solution of 3-(diphenylphosphino)-1-propylamine (566.8 mg, 2.33 mmol) in toluene (5 mL). More toluene (5 mL) was added to rinse. Then the dark-brown solution was heated in an oil bath at 100 C. for 16 h. The resulting brick-orange suspension was cooled to room temperature, and added to pentane (50 mL) with stirring. The yellow solid was collected by filtration, washed with pentane (2¡Á3 mL) and dried in vacuo to provide the desired complex (672.6 mg, 1.02 mmol, 95%) as a yellow-mustard solid. 31P{1H}-NMR analysis showed the presence of two species. 1H-NMR (CD2Cl2): delta (A) 7.19 (t, J=7.2 Hz, 4H), 7.14 (m, 8H), 7.05 (t, J=7.2 Hz, 8H), 3.28 (brs, 4H), 3.02 (brs, 4H), 2.66 (m, 4H), 2.0 (m, 4H). 13C-NMR (CD2Cl2): delta (A) 138.4 (t, J=19.2 Hz, Carom), 134.2 (t, J=4.8 Hz, CHarom), 129.0 (CHarom), 127.5 (t, J=4.8 Hz, CHarom), 41.3 (CH2), 26.9 (t, J=13.6 Hz, CH2), 24.7 (CH2). 31P{1H}-NMR (CD2Cl2): A (82%) delta=33.5 ppm (s), B (18%) delta=49.8 ppm (s).

15529-49-4, 15529-49-4 Dichlorotris(triphenylphosphino)ruthenium (II) 11007548, aruthenium-catalysts compound, is more and more widely used in various.

Reference£º
Patent; SAUDAN, Lionel; Dupau, Philippe; Riedhauser, Jean-Jacques; Wyss, Patrick; US2008/71121; (2008); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Dichlorotris(triphenylphosphino)ruthenium (II), cas is 15529-49-4, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,15529-49-4

General procedure: Diphosphine ligand (2.0 mmol) was dissolved in 10 mL of dichloromethane and the solution was added dropwise to a stirred solution of RuCl2(PPh3)3 (1.0 mmol) in 10 mL of dichloromethane. The reaction mixture was stirred approximately for 50 min at room temperature. The brown solution was filtered to remove the insoluble impurities. The solvent was reduced by a vacuum and the product was then precipitated by adding n-hexane. The yellow solid was filtered and washed three times with 20 mL of diethyl ether.

With the rapid development of chemical substances, we look forward to future research findings about 15529-49-4

Reference£º
Article; Al-Noaimi, Mousa; Warad, Ismail; Abdel-Rahman, Obadah S.; Awwadi, Firas F.; Haddad, Salim F.; Hadda, Taibi B.; Polyhedron; vol. 62; (2013); p. 110 – 119;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

15529-49-4, Dichlorotris(triphenylphosphino)ruthenium (II) is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

A mixture of [RuCl2(PPh3)3] (50 mg, 0.052 mmol) and bipy (10mg, 0.06 mmol) were charged in a two necked round bottomed flask and kept under vacuum for 15 min. 20 mL of dry acetone was then added and the brown mixture was stirred under argon atmosphere for approximately 30 min. A light yellowish-brown solid was precipitated that was filtered off, washed with diethylether (2 5 mL) and subsequently dried in vacuo. Yield: 90 %(40 mg). UV-Vis (e, Mu1 cm1): kmax (CH2Cl2) = 490 (5370), 350(9640).

15529-49-4, The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Zacharopoulos, Nikolaos; Kolovou, Evgenia; Peppas, Anastasios; Koukoulakis, Konstantinos; Bakeas, Evangelos; Schnakenburg, Gregor; Philippopoulos, Athanassios I.; Polyhedron; vol. 154; (2018); p. 27 – 38;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

246047-72-3, (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

246047-72-3, Example 52 Synthesis of Ru complex 6a To a 50 mL two-necked round bottom flask, after filling with Ar atmosphere, were added ligand 5a (l .Ommol) and CuCl (3.0mmol, 3eq) and 30 mL dry DCM, followed by refilling with Ar three times and protected with Ar balloon in close system. Ru complex lb (l.Ommol) was added under Ar protection, and the mixture was stirred for 0.5 hr at room temperature. After the reaction was complete, the solution was filtered and the filtrate was concentrated and slurred with silica gel. The crude was obtained by silica gel column chromatography and washed with methanol or pentane-DCM to obtain 453mg of yellow-green solid product 6a, yield: 79%. Ru complex (6a) 1HNMR (400 MHz, CDC13): delta 18.53 (s, 1H, Ru=CH), 8.59 (s, 1H), 7.28-6.49 (m, 11H), 4.160 (s, 4H, NCH2CH2N), 2.50 (s, 12H), 2.42 (s, 6H).; Example 59 Synthesis of Ru complex 6h The synthetic procedure is the same as in Example 52 in 1.0 mmol scale. 106 mg of yellow-green solid product 6h was obtained (37% yield). Ru complex (6h) 1HNMR (400 MHz, CDC13): delta 16.52 (s, 1H, Ru=CH), 8.43 (s,1H, N=CH), 8.10 (s, 1H), 7.46-7.22 (m, 2H), 7.73-6.96 (m, 8H), 4.19 (s, 4H, NCH2CH2N), 3.95 (s, 3H), 3.87 (s, 3H), 2.49 (s, 12H), 2.48 (s, 6H).

246047-72-3 (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 11147261, aruthenium-catalysts compound, is more and more widely used in various.

Reference£º
Patent; ZANNAN SCITECH CO., LTD.; ZHAN, James Zheng-Yun; WO2011/79439; (2011); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

15529-49-4, Dichlorotris(triphenylphosphino)ruthenium (II) is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

To a solution of ONS-LH (486mg, 2.0mmol) in THF (20mL) was added [Ru(PPh3)3Cl2] (868mg, 2.0mmol), which was then stirred under N2 for 15min. Triethylamine (Et3N) (202mg, 2.0mmol) was introduced, and the reaction mixture was stirred overnight at room temperature, during which the color of solution changed from brown to dark red brown. After removal of solvents in vacuo, CH2Cl2 (20mL) was added and the solution was filtered. The filtrate was concentrated and the residue was washed with Et2O (5mL¡Á2) and hexane (5mL¡Á2) to give the desired product. Recrystallization from MeOH/ Et2O (1:3) afforded dark red block crystals of 1¡¤0.5CH3OH¡¤2.75H2O suitable for X-ray diffraction in five days. Yield: 1.19g, 63% (based on Ru). IR (KBr disc, cm-1): 1597 (nuC=N), 1311 (nuC-O), 739 (nuC-S), 1432, 1087 and 691 (nuPPh3); 31P NMR (CDCl3, 162MHz): delta 16.4 (s, PPh3), 14.7 (s, PPh3) ppm. 1H NMR (CDCl3, 400MHz): delta 8.81 (s, 1H, CH=N), 7.98-7.31 (m, 4H, Ar-H), 7.23-7.06 (m, 4H, Ar-H), 6.75-7.01 (m, 30H, PPh3), 2.39 (s, 3H, SCH3) ppm. MS (FAB): m/z 903 [M+], 868 [M+-Cl], 641 [M+-PPh3], 379 [M+-2PPh3], 344 [Ru(ONS-L)]+. Anal. Calc. for C50H42NOP2ClSRu¡¤0.5(CH4O)¡¤2.75(H2O) (%): C, 64.74; H, 4.98; N, 1.48. Found: C, 64.67; H, 5.03; N, 1.43

15529-49-4, The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Wang, Chang-Jiu; Lin, Hui; Chen, Xin; Jia, Ai-Quan; Zhang, Qian-Feng; Inorganica Chimica Acta; vol. 467; (2017); p. 198 – 203;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, cas is 246047-72-3, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,246047-72-3

To a solution of 13b (40.0 mg, 0.065 mmol) in anhydrous CH2Cl2 (6.0 ml) was added2nd generation Grubbs catalyst (50.3 mg, 0.059 mmol) and CuCl (I) (13.0 mg, 0.13mmol) under nitrogen at 30 C and stirred for 3 h. The reaction mixture was concentrated in vacuo, and the residue was purified by column chromatography onsilica gel (hexane / AcOEt = 2 / 1) to give 3b (55.5 mg, 78%).green crystals; mp 160-165 C (dec.); 1H NMR (270 MHz, CDCl3) delta 2.01-2.04 (m, 2H),2.22-2.31 (m, 2H), 2.43 (d, J = 14.8 Hz, 18H), 2.77-2.87 (m, 4H), 4.10-4.21 (m, 6H),6.51 (s, 1H), 7.08 (s, 5H), 16.43 (s, 1H); 19F NMR (466 MHz, CDCl3) delta -80.5 (3F),-114.4 (2F), -121.5 (2F), -121.8 (4F), -122.5 (2F), -123.3 (2F), -126.0 (2F); 13C NMR(68 MHz, CDCl3) delta 19.2, 21.0, 22.5, 23.5, 51.7, 69.5, 77.5, 118.9, 124.1, 128.9, 129.5,133.2, 136.3, 138.7, 143.7, 148.5, 210.7, 291.4; IR (FT) 3905, 3857, 3816, 3743, 3700,3642, 3616, 3569, 3013, 2945, 2913, 2856, 2363, 2331, 1738, 1691, 1596, 1555, 1476,1455, 1413, 1245, 1203, 1140, 1108, 1035, 993, 915, 857, 814, 730 cm-1; HRMS (FAB)m/z [M+H]+ calcd for C41H40Cl2F17N2ORu 1072.1290, found 1072.1320.

With the rapid development of chemical substances, we look forward to future research findings about 246047-72-3

Reference£º
Article; Kobayashi, Yuki; Suzumura, Naoki; Tsuchiya, Yuki; Goto, Machiko; Sugiyama, Yuya; Shioiri, Takayuki; Matsugi, Masato; Synthesis; vol. 49; 8; (2017); p. 1796 – 1807;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, cas is 246047-72-3, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,246047-72-3

A suspension of 218 mg (0.26 mmol) of [RuCl2(PCy3) (ImH2Mes)(phenylmethy- lene)], 26 mg (0.26 mmol) copper chloride and 49 mg (0.29 mmol) 2-methyl-8-vinyl- quinoline in 17 ml methylene chloride was stirred at 300C for 90 min. The reaction mixture was evaporated to dryness and the isolated crude product purified by silica gel chromatography (hexane / ethyl acetat 7:3) and finally digested in 15 ml hexane at room temperature for 30 min to yield 157 mg (96%) of the title compound as green crystals. MS: 632.9 (M+). 1H-NMR (300 MHz, C6D6): 2.15 (s, 3H); 2.29 (s, 6H); 2.64 (s, 12H); 3.49 (s, 4H); 6.30 (d, J=8.4Hz, IH); 6.80 (t, J=7.3Hz, IH); 6.98 (s, 4H); 7.10 (d, J=8.4Hz, IH); 7.40 (d, J=8.1Hz, IH); 7.52 (d, J=7.0Hz, IH), 17.15-17.32 (br, IH). Anal, calcd. for C32H35N3Cl2Ru: C, 60.66; H, 5.57; N, 6.63; Cl, 11.19. Found: C, 60.33; H, 5.58; N, 6.27; Cl, 10.90.

With the rapid development of chemical substances, we look forward to future research findings about 246047-72-3

Reference£º
Patent; F. HOFFMANN-LA ROCHE AG; WO2008/644; (2008); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

246047-72-3, (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

Example 4 – Synthesis of the complex 3 according to the invention The commercially available complex G (1.0 g, 1.18 mmol) was placed in a flask, to which methylene chloride was added (24 ml). This was followed by adding the compound of the formula: (141 mg, 1.17 mmol) and tricyclohexylphosphine (330 mg, 1.18 mmol). The resulting solution was stirred at a temperature of 40C for 5 hours. The reaction mixture was introduced at the top of a chromatographic column packed with silica gel (eluent: ethyl acetate/cyclohexane, 0 to 10 vol. ). After evaporating the solvents, the complex 3 was obtained as a green solid (797 mg, 82% yield). The NMR data are consistent with Example 3.

246047-72-3, The synthetic route of 246047-72-3 has been constantly updated, and we look forward to future research findings.

Reference£º
Patent; APEIRON SYNTHESIS S.A.; SKOWERSKI, Krzysztof; BIENIEK, Micha?; WO2014/16422; (2014); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.

Wilkinson prepared cis-RuCl2(PPh3)2(NCPh)2 by the reaction of RuCl2(PPh3)3 with NCPh in acetone and characterized it by elemental analysis and infrared spectroscopy [1]. In our hands this compound can also be obtained by the reaction in toluene. A 0.099 g (0.10 mmol) sample of RuCl2(PPh3)3 was added to 0.032 mL (0.033 g, 0.32 mmol) of NCPh in 2 mL toluene. The resulting mixture was stirred rapidly for several seconds and immediately filtered. After 3-6 h at room temperature yellow crystals began to form. After about 24 h the supernatant was removed and the yellow crystalline RuCl2(PPh3)2(NCPh)2 was dried under vacuum to yield 0.093 g (0.10 mmol, 100%) of RuCl2(PPh3)2(C7H5N)2, m.p. = 186.5-187.9 C (dec), IR(KBr (cm-1): 3052 m, 2240 m, 2230 m, 2216 m, 1431 s, 1259 w, 1085 m, 1023 w, 740 s, 692 s, 512. 31P NMR (CDCl3): 25.6 s. X-ray quality crystals were obtained from a similar reaction that took place in an NMR tube in d-toluene.

15529-49-4, The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Cruz, Santina S.; Amenta, Donna S.; Gilje, John W.; Yap, Glenn P.A.; Polyhedron; vol. 114; (2016); p. 179 – 183;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is (1,3-Dimesitylimidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(VI) chloride, and cas is 301224-40-8, its synthesis route is as follows.,301224-40-8

General procedure: A mixture of fluorinated acid silver salt 6 (2.2eq.) and dichlororuthenium(IV) complex 5 (1.0eq.) was first dried under vacuum (13Pa) at room temperature for 1h. Dry dichloromethane (5mL) was added and the resulting mixture was stirred at room temperature for 3h in the dark. The solids were filtered off and washed with dry dichloromethane (2mL). Evaporation of the solvent afforded the product 7-9.

With the complex challenges of chemical substances, we look forward to future research findings about 301224-40-8,belong ruthenium-catalysts compound

Reference£º
Article; Babun?k, Mario; ?im?nek, Ond?ej; Ho?ek, Jan; Ryba?kova, Marketa; Cva?ka, Josef; B?ezinova, Anna; Kvi?ala, Jaroslav; Journal of Fluorine Chemistry; vol. 161; (2014); p. 66 – 75;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI