Introduction of a new synthetic route about 246047-72-3

With the rapid development of chemical substances, we look forward to future research findings about 246047-72-3

(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, cas is 246047-72-3, it is a common heterocyclic compound, the ruthenium-catalysts compound, its synthesis route is as follows.,246047-72-3

To a solution of 1-isopropoxy-4-(perfluorodecyl)-2-vinylbenzene (35.5mg, 0.052mmol) in dry CH2Cl2 (4 mL) was added Grubbs 2nd generation (48.75 mg, 0.057 mmol) and CuCl (I) (8.2 mg, 0.083 mmol) under N2 at 35C and stirred for 3 h. The reaction mixture was concentrated in vacuo, and the residue was purified by column chromatography on silica gel (hexane / CH2Cl2 = 1 / 1) to give 1a (39.5mg, 65%).

With the rapid development of chemical substances, we look forward to future research findings about 246047-72-3

Reference£º
Article; Kobayashi, Yuki; Inukai, Sae; Kondo, Natsuki; Watanabe, Tomoko; Sugiyama, Yuya; Hamamoto, Hiromi; Shioiri, Takayuki; Matsugi, Masato; Tetrahedron Letters; vol. 56; 11; (2015); p. 1363 – 1366;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI