As a common heterocyclic compound, it belongs to ruthenium-catalysts compound, name is Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II), and cas is 203714-71-0, its synthesis route is as follows.,203714-71-0
NHC ligand precursor 21 (9 mg, .03 mmol), KOz-Bu(F6) (6 mg, .03 mmol), and ruthenium complex 911 (13 mg, .02 mmol) were all combined in CgDbeta in a screw cap NMR tube in a glove box. The NMR tube was removed and heated at 600C for 2.5 hour in a fume hood. Conversion to catalyst 22 was determined to be 14% by proton NMR. 1H NMR (300 MHz, CDCl3) delta 17.19 (IH, s).
With the complex challenges of chemical substances, we look forward to future research findings about Dichloro(2-isopropoxyphenylmethylene)(tricyclohexylphosphine)ruthenium (II)
Reference£º
Patent; MATERIA, INC.; CALIFORNIA INSTITUTE OF TECHNOLOGY; WO2007/75427; (2007); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI